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Most projects relate to one of three areas: synthetic methods to construct structure-controlled macromolecules, self-healing polymers, or photoresponsive colloids. In general, our group uses the tools of synthetic and physical organic chemistry to address problems at the transplantation interface of chemistry and materials science. Molecular Disks, Ladders, and Grids State-of-the-art methods in nanofabrication transplantation are capable of creating structures and patterns with feature sizes below 10 transplantation nm. Given recent advances in the synthesis of shape-persistent molecular objects, it is now possible to imagine the placement of molecular functionality with atomic-scale precision over macroscopic dimensions. Our group is interested in developing efficient methods to prepare large, shape-persistent molecules that behave as rigid objects or nanoscale scaffolding. In addition to possible interest for nanoscale devices, these structures have potential applications in nanobiotechnology, nanofiltration membranes, 'smart-matrix' scaffolding for the construction of gradients to guide the migration of excitons and charges, and as anisotropic nanoparticles.
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